|Distribution and contamination status of heavy metals in estuarine sediments near Cua Ong Harbour, Ha Long Bay, Vietnam|
Ho, H.H.; Swennen, R.; Van Damme, A. (2010). Distribution and contamination status of heavy metals in estuarine sediments near Cua Ong Harbour, Ha Long Bay, Vietnam. Geol. Belg. 13(1-2): 37-47
In: Geologica Belgica. Geologica Belgica: Brussels . ISSN 1374-8505, more
heavy metal, sediment, distribution, controlling factor, contamination status
The distribution, controlling geochemical factors and contamination status of heavy metals in estuarine sediments near Cua Ong Habor, Ha Long Bay (Vietnam) were investigated. 36 surface sediment samples were collected and analyzed for major elements (Al, Ca, Fe, K, Mg, S), heavy metals (As, Cd, Co, Cr, Cu, Mn, Ni, Pb and Zn), organic matter, loss on ignition (LOI), grain size composition and pH. Spatial distribution patterns of heavy metals as well as their controlling factors were elucidated based on geochemical mapping and statistical methods such as the Pearson ProductMoment linear correlation and Factor Analysis. The results illustrated that the distribution patterns of As, Cd, Cr, Cu, Ni, Pb and Zn are mainly controlled by organic matter and clay minerals and determined by the distribution of the finegrained fraction (F < 63 µm) in the sediments. In contrast, Fe and Mn compounds seem to exert some control on the distribution of Co. Carbonates partly control the distribution of Mn, but are not important with respect to the other studied heavy metals. The contamination status by heavy metals was assessed based on comparison with Canadian, Wisconsin- United States and Flemish numerical Sediment Quality Guidelines, and calculation of Geo-accumulation Index (Igeo) and Enrichment Factor (EF). The results indicated that natural processes such as weathering and erosion of bedrock are the main supply sources of heavy metals in sediments near Cua Ong Harbor. Among the studied heavy metals, only As is of concern whereas Cd, Co, Cr, Cu, Mn, Ni, Pb and Zn seem to reflect their background concentrations in sediments of Ha Long Bay.