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Lyngbyaloside, a novel 2,3,4-tri-O-methyl-6-deoxy-alpha-mannopyranoside macrolide from Lyngbya bouillonii (Cyanobacteria)
Klein, D.; Braekman, J.C.; Daloze, D.; Hoffmann, L.; Demoulin, V. (1997). Lyngbyaloside, a novel 2,3,4-tri-O-methyl-6-deoxy-alpha-mannopyranoside macrolide from Lyngbya bouillonii (Cyanobacteria). J. Nat. Prod. 60(10): 1057-1059. dx.doi.org/10.1021/np9702751
In: Journal of Natural Products. American Chemical Society/American Society of Pharmacognosy: Washington, DC, etc.. ISSN 0163-3864, more
Peer reviewed article  

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Keyword
    Marine

Authors  Top 
  • Klein, D.
  • Braekman, J.C.
  • Daloze, D.
  • Hoffmann, L.
  • Demoulin, V.

Abstract
    A novel 16-membered macrolide linked to a 2,3,4-tri-O-methyl-6-deoxy-alpha-mannopyranoside, lyngbyaloside (1), has been isolated from the blue-green alga Lyngbya bouillonii, collected on Laing Island (Papua New Guinea). Its structure has been established by a detailed high-field 2D NMR study. The relative configuration of 8 out of the 13 stereogenic carbon atoms is proposed from the analysis of NOE difference experiments.

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