Anthracene

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Definition of anthracene:
Anthracene forms part of a wide group of polyaromatic hydrocarbons. Of this group antracene is one of the more toxic ones. [1]
This is the common definition for anthracene, other definitions can be discussed in the article


Notes

Natural state and human emission

Anthracene
Anthracene
Formula
C14H10

Anthracene is used as an intermediate compound for the manufacturing of dyes and polyradicals used to make resins. It may also be used as a diluent for wood protection products, an insecticide, or a fungicide. Furthermore, anthracene is an organic cristallized photoconductor used in electrophotography.

In the nature, anthracene can be found to a small degree in fossil fuels (12 g/kg of coal). It is also present in fuel (100 to 300 mg/L) and petrol (1.55 mg/L, to 2,6 mg/L in high-octane petrols)[2].

The main sources of anthropic emissions are the following:

  • tailpipes of car motors (0.02 to 6.45 μg/m3)[3];
  • cokefaction and gaseifaction of coal and more generally emissions of coal kilns and fuel kilns;
  • purification of petrol;
  • use of impregnation oils for wood treatment;
  • production of asphalt for roads covering;
  • smoke of wood coal;
  • combustion of pneumatic wastes (rubber).

Behaviour

In water, anthracene is easily adsorbed on particles in suspension. However, it may also volatilize, which means its final amount is the result of two processes in competition. In soils, anthracene does not move very much: it may volatilize from moist soils, but only very little from dry ones.[4]

In distilled water, anthracene is destroyed by photolysis in several hours when it is exposed to natural light. However, the substance is not biodegradable: after 28 days in living organisms, only 1.9% of the substance is destroyed.[5]

Anthracene may also bioaccumulate in aquatic organisms, as in some organisms it can be absorbed 10.000 times faster than eliminated. [6][7][8]

Effects on health

One of the most common ways to be contaminated by anthracene is through breathing contaminated air. If one eats food which contains anthracene or drinks polluted water, he can also ingest anthracene. Researches have proven that another source of exposure is the simple contact of the skin with contaminated soil or products like heavy oils, coal tar, roofing tar or creosote (oily liquid found in coal tar and used to preserve wood). Target organs reached by anthracene include the kidneys, the liver and fat.

Once inside a body, anthracene seems to target skin, blood, stomach, intestines and the lymph system. Exposure to high doses of anthracene for a short time can cause damage to the skin, like burning, itching and edema, a build up of fluid in tissues. Humans exposed to anthracene experienced headaches, nausea, loss of appetite, inflammation or swelling of the stomach and intestines. In addition, their reaction time slowed and they felt weak.

Other effects have been found to occur on animals, like reproductive problems, birth defects after an exposure of a pregnant test subject to the substance, and damage to the immune systems. However, these effects have not been seen on humans until now.

Nevertheless, no experience has proven anthracene to be a cancer causing substance yet.


Environmental standards and legislation

Included (as polyaromatic hydrocarbons) in the OSPAR list of substances of priority action

Included in the water framework list of priority substances


See also

Anthracene on the ED North Database

OSPAR background document on polyaromatic hydrocarbons


References

  1. Kennish, M. J. (1996): Practical Handbook of Estuarine and Marine Pollution, CRC Press 524 pp
  2. Verschueren K. (1996) - Anthracene. Handbook of Environmental Data on Organic Chemicals. New York, Van Nostrand Reinhold Co. 3rd Ed, pp. 214-217
  3. OMS IPCS (1998) - Environmental Health Criteria 202: Selected Non-Heterocyclic Policyclic Aromatic Hydrocarbons. World Health Organisation, International Programme on Chemical Safety. http://www.inchem.org/fullist.htm
  4. HSDB (2001) - Polycyclic Aromatic Hydrocarbons - Anthracene. Hazardous Substances Data Bank, National Library of Medicine.
  5. Callahan M.A., Slimak M.W., Gabel N.W., May I.P., Fowler C.F., Freed J.R., Jennings P., Durfee R.L., Whitmore F.C., Maestri W.R., Mabey B.R. and Holt B.R. (1979) - Water-related environmental fate of 129 priority pollutants Volume II. Halogenated aliphatic hydrocarbons, halogenated ethers, monocyclic aromatics, phtalates esters, polycyclic aromatic hydrocarbons, nitrosamines, miscellaneous compounds. United States Environmental Protection Agency. Washington, DC. EPA-440/4-79-029b.
  6. Spacie A., Landrum P. and Leversee G. (1983) - Uptake, depuration, and biotransformation of anthracene and benzo[a]pyrene in bluegill sunfish. Ecotoxicol Environ Saf, 7, 330-341.
  7. Linder G., Bergman H. and Meyer J. (1985) - Anthracene bioconcentration in rainbow-trout during single-compound and complex-mixture exposures. Environ Toxicol Chem, 4, 549-558.
  8. CITI (1992) - Biodegradation and Bioaccumulation data of existing chemicals based on the CSCL Japan. Chemicals Inspection and Testing Institute. Japan. October 1992.