Difference between revisions of "Cyclododecane"

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{{ Definition|title= cyclododecane
 
{{ Definition|title= cyclododecane
  
|definition=Cyclododecane is a saturated, alicyclical hydrocarbon. <ref>[http://www.cyclododecane.net www.cyclododecane.net]/</ref>}}
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|definition=Cyclododecane is a saturated, alicyclical hydrocarbon<ref>[http://www.cyclododecane.net www.cyclododecane.net]/</ref>. }}
  
 
== Notes ==
 
== Notes ==
  
There are 2 main uses for cyclododecane: as an intermediate for the production of hexabromo cyclododecane (which is a [[flame retardant]]) a
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{| class="toccolours" border="1" style="float: right; clear: right; margin: 0 0 1em 1em; border-collapse: collapse;"
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! bgcolor="#FF8888" | Cyclododecane
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|-
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| align="center" bgcolor="#FFFFFF" | [[Image:CDD.JPG|100px|Cyclododecane ]]  
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|-
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! bgcolor="#8888FF" | Formula
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|-
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| align="center" | C<sub>12</sub>H<sub>24</sub>
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|-
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|}
  
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There are 2 main uses for cyclododecane. It can be used as an intermediate, e. g. for the production of [[flame retardant|flame retardants]], cleaning and washing agents and other chemicals. It can also be used as a binding medium for temporarily sealing, consolidation and conservation of weak or friable materials in the field of excavation and transport of archaeological objects<ref name="eca">[http://echa.europa.eu/doc/about/organisation/msc/agreements_svhc/svhc_supdoc_cyclododecane.pdf European Chemicals Agency 8 October 2008 Support document for agreement on cyclododecane] </ref>.
  
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It is very [[persistent]] in the environment. It's not hydrolysed [[abiotic|abiotically]] and also not easily biodegraded. Considering that it is highly lipofylic, cyclododecane is considered to be mostly [[adsorption|adsorbed]] to suspended particles and soils. It is also very [[volatile]], causing the dissolved cyclododecane to evaporate rapidly to the atmosphere. Without adsorption, the [[half-life]] of cyclododecane in a small pond (by evaporation) would be less than 4 hours.  Due to this adsorption the real half-live is 48 days. If released to the atmosphere, cyclododecane will be abiotically degraded.
  
Cyclododecane may  be  released  to the  environment  in  wastewater  streams, fugitive  emissions  generated at sites of its industrial production and sites of its use (Hall Howard, 1997). If released to  soil, it is not expected  to  leach. If released to water, it may volatilize and partition to sediment.   
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Cyclododecane has a very high potential to [[bioaccumulation|bioaccumulate]], although there is no information available on its ability to [[biomagnification|biomagnify]] through [[food chain|food chains]].
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Concentrations above 1 mg/l cause acute [[toxic|toxicity]] in [[pollution and pelagic fishes|fishes]], concentrations above 2 mg/l acute toxicity in aquatic invertebrates<ref name="eca">[http://echa.europa.eu/doc/about/organisation/msc/agreements_svhc/svhc_supdoc_cyclododecane.pdf European Chemicals Agency 8 October 2008 Support document for agreement on cyclododecane] </ref>.   
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<P>
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<BR>
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<P>
  
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== Environmental standards and legislation ==
  
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[[OSPAR List of priority substances|Included in the OSPAR list of substances of priority action]]
  
  
  
If released to the atmosphere, cyclododecane will abiotically be degraded. The rate constant for the
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==References==
vapour-phase reaction of cyclododecane with photochemically produced hydroxyl radicals has been
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<references/>
estimated  to be 1,67.10-11 cm3 /molecule-sec at 25°C, wich corresponds  to an atmospheric half-life
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of about 23hr and a atmospheric concentration of 5.105
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{{author
hydroxyl radicals par cm3
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|AuthorID=19826
(Atkinson, 1987). 
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|AuthorFullName=Daphnis De Pooter
Reaction  half-life  with OH-radicals  in  the  atmosphere was  estimated  at  22.7  hours  by AopWin
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|AuthorName=Daphnisd}}
v1.91 (5*105 OH cm-3; 24 h day-1
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[[Category:Coastal and marine pollution]]
). No estimate for reaction with ozone was provided by the model.
 
Alkanes are generally resistant to aqueous environmental hydrolysis (Lyman et al, 1990); therefore,
 
cyclododecane is not expected to hydrolyze in the environment.
 

Revision as of 17:39, 19 March 2013

Definition of cyclododecane:
Cyclododecane is a saturated, alicyclical hydrocarbon[1].
This is the common definition for cyclododecane, other definitions can be discussed in the article

Notes

Cyclododecane
Cyclododecane
Formula
C12H24

There are 2 main uses for cyclododecane. It can be used as an intermediate, e. g. for the production of flame retardants, cleaning and washing agents and other chemicals. It can also be used as a binding medium for temporarily sealing, consolidation and conservation of weak or friable materials in the field of excavation and transport of archaeological objects[2].

It is very persistent in the environment. It's not hydrolysed abiotically and also not easily biodegraded. Considering that it is highly lipofylic, cyclododecane is considered to be mostly adsorbed to suspended particles and soils. It is also very volatile, causing the dissolved cyclododecane to evaporate rapidly to the atmosphere. Without adsorption, the half-life of cyclododecane in a small pond (by evaporation) would be less than 4 hours. Due to this adsorption the real half-live is 48 days. If released to the atmosphere, cyclododecane will be abiotically degraded.

Cyclododecane has a very high potential to bioaccumulate, although there is no information available on its ability to biomagnify through food chains. Concentrations above 1 mg/l cause acute toxicity in fishes, concentrations above 2 mg/l acute toxicity in aquatic invertebrates[2].


Environmental standards and legislation

Included in the OSPAR list of substances of priority action


References

The main author of this article is Daphnis De Pooter
Please note that others may also have edited the contents of this article.

Citation: Daphnis De Pooter (2013): Cyclododecane. Available from http://www.coastalwiki.org/wiki/Cyclododecane [accessed on 25-04-2024]