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Snow and sea ice melt enhance under-ice pCO2 undersaturation in Arctic waters
Verdugo, J.; Ruiz-Castillo, E.; Rysgaard, S.; Boone, W.; Papakyriakou, T.; Geilfus, N.-X.; Sørensen, L.L. (2025). Snow and sea ice melt enhance under-ice pCO2 undersaturation in Arctic waters. J. Mar. Sci. Eng. 13(12): 2257. https://dx.doi.org/10.3390/jmse13122257
In: Journal of Marine Science and Engineering. MDPI: Basel. ISSN 2077-1312; e-ISSN 2077-1312
Peer reviewed article  
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Author keywords
    under-ice pCO2; high-frequency pCO2 measurements; snow and sea ice meltwater; Arctic; phytoplankton blooms; internal consistency; carbonic-acid; dissociation; constants; meltwater; seawater; svalbard; drivers; summer
Authors  Top 
  • Verdugo, J.
  • Ruiz-Castillo, E.
  • Rysgaard, S.
  • Boone, W.
  • Papakyriakou, T.
  • Geilfus, N.
  • Sørensen, L.L.
Abstract
    The decline in Arctic summer sea ice alters air-sea gas exchange. Because the Arctic Ocean accounts for 5%-14% of global oceanic carbon uptake, understanding how sea ice melt impacts the ocean's carbon sink capacity is central to constraining future fluxes. In this study, we focus on Young Sound-Tyrolerfjord in Northeast Greenland to examine the sea ice-ocean interaction during the transition from melt onset to melt pond drainage. High-frequency measurements of partial pressure of CO2 (pCO2) and seawater physical properties were taken 2.5 m below the sea ice. Our results reveal that pCO2 in the seawater was undersaturated (248-354 mu atm) compared to the atmosphere (401 mu atm), showing that the seawater has the potential to take up atmospheric CO2 as the sea ice breaks up. The pCO2 undersaturation was attributed to dilution resulting from mixing meltwater from snow and sea ice with the under-ice seawater. Additionally, the drainage of melt pond water that had been in contact with the atmosphere into the under-ice seawater further lowered pCO2. Melt pond drainage represents an initial connection between the atmosphere and under-ice seawater through meter-thick sea ice during the summer thaw. Our study demonstrates that snow and sea ice melt reduce pCO2 in under-ice seawater, enhancing its potential for atmospheric CO2 uptake during sea ice breakup.
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